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A new type of photolabile, surface-initiated, atom-transfer radical polymerization (SI-ATRP) initiator 3-(2-bromo-2-methylpropanamido)-3-(2-nitrophenyl)propanoic acid was synthesized, and immobilized via an aminosilane linker onto a flat silicon surface. Poly(lauryl methacrylate) and polystyrene brushes were grown from the surface via SI-ATRP, and the surface-tethered polymer chains cleaved off under UV irradiation. The kinetics of the cleavage process were investigated, and an apparent effect of osmotic forces within the polymer brush could be observed. The molecular weight of the cleaved polymers could be readily determined by means of size-exclusion chromatography.
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Kang et al. (2013) studied this question.
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