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Regioselective carbon-carbon bond formation by radical reaction at the β-position of β-alkoxyacrylate was applied to a synthesis of 2,5-disubstituted tetrahydrofuran, 2,6-disubstituted tetrahydropyran, 2,7-disubstituted oxepane derivatives.
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Yuasa et al. (1997) studied this question.
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