The first triorganosulfonium azides [Me3S]N3 and [Ph3S]N3 were prepared by reaction of the corresponding sulfonium bromides/iodides with silver azide and characterized by spectroscopic methods. The molecular structure of [Ph3S]N3 as well as that of the precursor, [Ph3S]Br, have been determined by X-ray diffraction.
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Klapötke et al. (2009) studied this question.
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