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The value of tmax in differential scanning calorimetry is correlated with the crystallization kinetics of poly(ethylene terephthalate) (PET). The Avrami exponent, n, obtained varies as a result of a change in slope of the curve at the point tn, a secondary crystallization transition. The plot of tn vs. tmax shows a linear relationship. The rate of crystallization depends upon both molecular weight and crystallization temperature. Under a nucleation controlling step, the plot of log tmax vs. {article}{empty}{document}tₘₐₓ vs.1T² Δ T{document} gives a linear relationship. Theoretical concepts of the treatment are discussed.
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Chun‐Hsien Lin (1983) studied this question.
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