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Abstract μ-Alkoxo-μ-pyrazolato-bridged binuclear nickel(II) complexes with 1,3-bis(salicylideneamino)-2-propanol (H3La), 1,4-bis(salicylideneamino)-2-butanol (H3Lb), and 1,5-bis(salicylideneamino)-3-pentanol (H3Lc), Ni2(La)(pz), Ni2(Lb)(pz), and Ni2(Lc)(pz) (pz = pyrazolate anion), have been prepared and characterized by elemental analyses, infrared and electronic spectra, and magnetic susceptibilities. The molecular structures of these complexes were determined by the single-crystal X-ray structure analyses. The planarities of the molecules were discussed in relation to the variation of the chain lengths of the Schiff bases.
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Mikuriya et al. (1992) studied this question.
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