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The room temperature rate coefficient for the reaction Br+Br2O→Br2+BrO (3) has been measured using the technique of pulse-laser photolysis with long-path transient absorption detection of the BrO reaction product. A value of k3=(2.0±0.5)×10−10 cm3 molecule−1 s−1 was determined. The photolysis products of Br2O at 308 nm were also examined.
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James B. Burkholder (1998) studied this question.
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