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Photochemical reduction of complexed Ag+ ions to stable complexed Ag atoms can be accomplished with the aid of the heterocycle (1), which combines the properties of a crown ether and of a surfactant. (1) Ag+ is formed spontaneously from (1) and AgNO3; reduction with visible light requires a cyanine dye as sensitizer.
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Humphry‐Baker et al. (1979) studied this question.
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