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Tales of the unexpected: Transfer of a nitroxyl group from R2N-NONOates to aquacobalamin to form nitroxylcobalamin does not proceed via H+-catalyzed R2N-NONOate decomposition, but instead occurs via a probable NONOate-cobalamin intermediate (see scheme; r.d.s.=rate-determining step).
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Hassanin et al. (2009) studied this question.
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