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Bis(tosyl)imidoruthenium(VI) porphyrin complexes are prepared and characterised by spectroscopic means; [Ru VI - (tpp)(NTs) 2 ] can undergo imido group transfer reactions with alkenes to afford aziridines, as well as C–H bond oxidation of benzyl alcohol to give benzaldehyde; a tosylamido ruthenium(IV) complex is also isolated and characterised by X-ray diffraction.
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Au et al. (1997) studied this question.
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