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The power of two: μ-η2:η2-Peroxodicopper(II) complexes with hexadentate diaminotetrabenzimidazole ligands can catalyze the sulfoxidation of aromatic sulfides by a direct oxygen-transfer mechanism (see scheme) in the presence of a sacrificial co-substrate, similarly to the enzyme tyrosinase. The yields and turnover numbers depend on the sulfide and co-substrate concentrations and the electron density on the sulfide S atom.
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Gamba et al. (2009) studied this question.
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