The oxidization process of the Fe–Ni mixed Prussian blue analogue (Fe0.2Ni0.8)[Fe(CN)6]0.67·zH2O was investigated by means of valence-differential spectroscopy. The spectroscopy revealed that the oxidization process selectively starts from the intermediate clusters. With a further increase in the oxidization level, all intermediate clusters are oxidized, and then Fe-rich clusters begin to be oxidized. On the basis of these results, we will discuss the redox process of the Ni–Fe cyano mixed crystal.
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Omura et al. (2011) studied this question.
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