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Copper dispersed on Ca 5 (PO 4 ) 3 OH has been identified as an excellent heterogeneous catalyst for the in situ generation of ‘CN’ from NH 4 HCO 3 and N , N -dimethylformamide, in the C–H bond activation of 2-phenylpyridine.
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Boosa et al. (2016) studied this question.
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