The thermodynamic parameters ΔH0, ΔG0 and ΔS0 – and thereby the equilibrium constants – for the complexation of the carrier antibiotics nigericin and monensin with sodium and potassium ions in methanol at 25°C have been determined by microcalorimetry. The results are discussed in terms of the nature of the interaction between ligands and cations.
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Lutz et al. (1971) studied this question.
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