Specific complexation in biological systems is based to a large extent on electron donor-acceptor interactions, the importance of which have been demonstrated quantitatively in the model system consisting of the host molecule 1 and 2,6-disubstituted naphthalenes. The electron-rich compound 1 forms the best complexes with naphthalene derivatives having two acceptor substituents.
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Ferguson et al. (1986) studied this question.
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