Effects of molecular orientation on surface-plasmon-coupled emission patterns

We observed azimuthal distributions of surface-plasmon-coupled emission from thin layers of randomly oriented and oriented sexithiophene molecules deposited on 50-nm-thick Ag films. For the randomly oriented layer, we observed a uniform and isotropic cone of emission, showing that the surface plasmons are excited isotropically in all directions on the Ag surface. The emission pattern for the oriented layer exhibited a much stronger intensity along the direction of molecular orientation, showing that surface plasmons propagating parallel to the molecular orientation are excited most effectively. These results demonstrate that surface-plasmon-coupled emission provides a new simple approach to the determination of molecular orientation in thin films.