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September 5, 2026ACS Applied Polymer Materials

Building a “Multi-Level Synergistic” Flame Retardant Barrier for Epoxy Resins: An Innovative Strategy Combining Inorganic Catalyzed Carbonization with Hydrogen-Bonded Organic Frameworks

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Authors

YCYumeng CuiLWLiyong WangZZZhe Zheng

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Overview

Experimental study demonstrates enhanced fire resistance and smoke suppression in epoxy resins, suggesting an effective strategy to resolve the trade-off with mechanical performance.

Key Points

  • To develop an epoxy resin composite that achieves superior flame retardancy, smoke suppression, and thermal conductivity without degrading mechanical properties.
  • Exfoliated hexagonal boron nitride (h-BN) nanosheets using green mechanical ball milling.
  • Constructed a molybdenum phosphide (MoP) catalytic layer and a P–N-containing hydrogen-bonded organic framework (PA-HOF) sequentially in situ on h-BN nanosheets to form a core-shell h-BN@MoP@PA-HOF additive.
  • Incorporated the composite additive into an epoxy resin matrix at 4 phr and 12 phr loadings to evaluate flame retardancy, smoke release, thermal conductivity, and mechanical performance.
  • Epoxy resin containing 4 phr additive reduced peak heat release rate by 54.27%, smoke production rate by 48.98%, and total smoke release by 31.59%, with marked decreases in CO and CO2 production and no substantial loss in mechanical properties.
  • Epoxy resin containing 12 phr additive achieved a UL-94 V-1 rating and exhibited a 36.68% enhancement in thermal conductivity.

Cite This Study

Cui et al. (2026) studied this question.

synapsesocial.com/papers/6a9bd4726b95aff0620ec305https://doi.org/10.1021/acsapm.6c03021
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Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Bioinspired Hierarchical Interface Engineering: Towards High‐Efficiency Flame‐Retardant and Smoke‐Suppressing Epoxy Composites2025
  2. 2Harnessing an Eco‐Friendly <scp>P</scp> – <scp>N</scp> Monocomponent Derived From Phytic Acid for Superior Fire Protection of Epoxy Resins2026
  3. 3Modification of Red Phosphorus Flame Retardant via Hydrolytic Microencapsulation: Thermo‐Chemical Behavior Regulation and Flame‐Retardant Mechanism Investigation in Epoxy Composites2026 · 2 citations
  4. 4Intercalated Organically Modified Montmorillonite for Flame Retardancy of Aramid Reinforced Epoxy Resin Composites2026
  5. 5Synergistic Flame Retardancy of Epoxy Resin with Aminated Multi-Walled Carbon Nanotubes and Ammonium Polyphosphate2026 · 1 citations