this paper represents one of the very few known photochemical reactions involving reduced flavin.Other examples include the photoalkylation of reduced flavin bound to lactate oxidase32 and the photodehalogenation reactions observed with reduced 7-and 8-halogen-substituted flavins.33Acknowledgment.We thank Drs. Wallace Ashton and Franz Muller for gifts of 1-deazariboflavin and 7,8-dimethyl-1 ,loethyleneisoalloxazium perchlorate, respectively.We are grateful to Dr.
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Nijhuis et al. (1987) studied this question.