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January 1, 1998Chemical Communications

Discovery that quinoline and triphenylphosphine alter the electronic properties of hydrogenation catalysts

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Abstract

Quinoline and triphenylphosphine are found to influence the polarisation of the palladium–hydrogen bond in heterogeneous hydrogenation; this provides a possible explanation for why the addition of these compounds increases the selectivity of the semi- reduction of alkynes.

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Cite This Study

Jin‐Quan Yu (1998) studied this question.

synapsesocial.com/papers/6a9bf3fbc4ca1e4d5c68ef90 https://doi.org/10.1039/a800629f

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