The effect of initiation and propagation rate constant ratio on the statistical character of termination‐free anionic polymers is discussed. For obtaining the expressions for the size distribution and the averages, we have followed a mathematical procedure which might prove useful in the treatment of more complicated problems. The conditions under which the ultimate polymer has an appreciable or negligible inhomogeneity are clearly stated.
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Nanda et al. (1964) studied this question.
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