The X-ray structure of [Agn(PhSCH2CH2CH2SPh)2n]n+ shows an infinite array of tetrahedral AgI atoms coordinated via one S-donor of four distinct PhSCH2CH2CH2SPh ligands, whereas [Agn(MeSCH2CH2CH2SMe)n]n+ is a chain polymer involving trigonal (µ2-S)2, S ligation with one S-donor bridging two adjacent AgI centres while the other S-donor of the dithioether ligand is non-bridging.
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Black et al. (1995) studied this question.
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