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The reaction of 1-(SH)-1,2-C2B10H11 with [Ag(O3SCF3)(PPh3)] led to the tetranuclear species [Ag4(SC2B10H10)2(μ-O−O)2L4] (O−O = CF3SO3; L = PPh3) whose crystal structure revealed a four-membered ring of alternating sulfur and silver atoms. The other two silver centers are exocyclically bonded to the thiolate, which thus acts as a triply bridging ligand.
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Artigas et al. (1997) studied this question.
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