Steric control of aggregation in neutral silver(I) thiolates, [AgSR]n. Crystal and molecular structures of [AgSCH(SiMe3)2]8, a discrete molecular biscycle of weakly interacting [AgSCH(SiMe3)2]4 units, and of [AgSC(SiPhMe2)3]3 and [AgSC(SiMe3)3]4, discrete molecular monocycles containing linearly coordinated silver(I) and doubly bridging mercapto sulfur donors from novel sterically hindered thiolate ligands. A comparison with the nonmolecular structure of [Ag4{SCH2(SiMe3)}3]n1

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSteric control of aggregation in neutral silver(I) thiolates, [AgSR]n. Crystal and molecular structures of [AgSCH(SiMe3)2]8, a discrete molecular biscycle of weakly interacting [AgSCH(SiMe3)2]4 units, and of [AgSC(SiPhMe2)3]3 and [AgSC(SiMe3)3]4, discrete molecular monocycles containing linearly coordinated silver(I) and doubly bridging mercapto sulfur donors from novel sterically hindered thiolate ligands. A comparison with the nonmolecular structure of [Ag4{SCH2(SiMe3)}3]n1Kaluo Tang, Mohammad Aslam, Eric Block, Terrence Nicholson, and Jon ZubietaCite this: Inorg. Chem. 1987, 26, 10, 1488–1497Publication Date (Print):May 1, 1987Publication History Published online1 May 2002Published inissue 1 May 1987https://pubs.acs.org/doi/10.1021/ic00257a007https://doi.org/10.1021/ic00257a007research-articleACS PublicationsRequest reuse permissionsArticle Views312Altmetric-Citations99LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts