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A series of dimethyl compounds of Ti(IV) have been isolated containing both cyclopentadiene and ortho-arylphenoxide ligation; reaction with [B(C6F5)3] generates corresponding cationic methyl species which eliminate methane and form [Cp(ArO)Ti{CH2B(C6F5)2}(C6F5)] derivatives.
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Thorn et al. (1998) studied this question.
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