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February 3, 1997Angewandte Chemie International Edition in English

Thermal Decomposition of [(η5‐C5Me5)TiMe3]: Synthesis and Structure of the Methylidyne Cubane [{(η5‐C5Me5)Ti}4(μ3‐CH)4]

Román Andrés Pilar Gómez‐Sal Ernesto de Jesús Avelino Martı́n Miguel Mena Carlos Yélamos

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Abstract

An almost perfect Ti4C4 cube is present in compound 1, which is formed by methane elimination from [Cp*TiMe3] at 95°C. Compound 1 is a dark brown crystalline solid that is stable in solution in toluene at 200°C for several days. Cp* = C5Me5.

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Andrés et al. (1997) studied this question.

synapsesocial.com/papers/6a9c6f02c1325273a92245a2 https://doi.org/10.1002/anie.199701151

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