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A practically simple, highly enantioselective Brønsted acid catalyzed α-aminoxylation of enecarbamates extends the substrate scope for the α-aminoxylation to linear and aromatic ketones, allowing convergent and stereoselective access to valuable α-hydroxy ketones, β-amino alcohols, and cis-oxazolidinones.
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Lu et al. (2010) studied this question.
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