Preresonance Raman studies of poly( L ‐lysine), poly( L ‐glutamic acid), and deuterated N‐methylacetamides

The Raman spectra of poly(L‐lysine) with various structures, ionized poly(L‐glutamic acid), and deuterated N‐methylacetamides have been observed using visible and the 257.3‐nm laser lines as the light source. Most of the Raman bands with significantly enhanced intensities in the uv‐excited spectra of the polymers have been assigned to the vibrations associated with the CO and C–N stretching modes, the amide I, II, III, I′, II′, and III′, with reference to the results obtained for simple amide molecules including the deuterated N‐methylacetamides. Several amide frequencies have been newly identified and the structures of the polymers have been discussed through the comparison of the Raman and ir amide frequencies.