Fabrication of Ultra‐Durable and Flexible NiP x ‐Based Electrode toward High‐Efficient Alkaline Seawater Splitting at Industrial Grade Current Density

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Designing nonprecious metal‐based electrocatalysts to yield sustainable hydrogen energy by large‐scale seawater electrolysis is challenging to global emissions of carbon neutrality and carbon peaking. Herein, a series of highly efficient, economical, and robust Ni–P‐based nanoballs grown on the flexible and anti‐corrosive hydrophobic asbestos (NiP x @HA) is synthesized by electroless plating at 25 °C toward alkaline simulated seawater splitting. On the basis of the strong chemical attachment between 2D layered substrate and nickel‐rich components, robust hexagonal Ni 5 P 4 crystalline modification, and fast electron transfer capability, the overpotentials during hydrogen/oxygen evolution reaction (HER/OER) are 208 and 392 mV at 200 mA cm −2 , and the chronopotentiometric measurement at 500 mA cm −2 lasts for over 40 days. Additionally, the versatile strategy is broadly profitable for industrial applications and enables multi‐elemental doping (iron/cobalt/molybdenum/boron/tungsten), flexible substrate employment (nickel foam/filter paper/hydrophilic cloth), and scalable synthesis (22 cm × 22 cm). Density functional theory (DFT) also reveals that the optimized performance is due to the fundamental effect of incorporating O‐source into Ni 5 P 4 . Therefore, this work exhibits a complementary strategy in the construction of NiP x ‐based electrodes and offers bright opportunities to produce scalable hydrogen effectively and stably in alkaline corrosive electrolytes.