Catalytic hydrogenolysis of the C−F bond in most unreactive monofluoroarenes readily occurs under mild conditions, in the presence of homogeneous and/or heterogeneous Rh catalysts generated from [(Cy 3 P) 2 Rh(H)Cl 2 ], H 2, and aqueous alkali.
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Young et al. (1999) studied this question.
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