Various 1‐substituted cyclopentylamines (25 examples, 10–89 % yield) have been prepared according to a one‐pot procedure by the addition of tetramethylenebismagnesium dibromide in the presence of Ti(OiPr)4 to aliphatic, aromatic and heteroaromatic nitriles, respectively.
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Tomashenko et al. (2010) studied this question.
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