All in one: CuBr/iminopyridine systems can catalyze simultaneously both copper(I)-catalyzed azide–alkyne cycloaddition (CuAAC, “click”) and living radical polymerization (LRP) processes (see scheme). The relative rate of the two processes can be tailored by a judicious choice of the reaction conditions (solvent, temperature, [CuBr]0) leading to the development of a potentially very efficient synthetic route to well-defined functional polymers.
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Geng et al. (2008) studied this question.
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