⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

January 1, 1999Journal of the Chemical Society Perkin Transactions 1

Highly chemoselective α-diazo carbonyl insertion reactions into N–H and S–H bonds catalysed by [RuCl(η5-C5H5)(PPh3)2]

Alessandro Del Zotto Walter Baratta Pierluigi Rigo

View at Publisher

Ask AI

Bookmark

Share

Ask about this paper

Answers are grounded in this paper and cite their sources.

Ask your own question…

Abstract

Complex [RuCl(η5-C5H5)(PPh3)2], in chloroform at 60 °C, catalyses the chemoselective insertion of α-diazo carbonyl compounds into N–H and S–H bonds to afford α-keto-amines and α-keto-thioethers.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Zotto et al. (1999) studied this question.

synapsesocial.com/papers/6a9d5cb734685bd77029fdcc https://doi.org/10.1039/a906332c

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 10 related papers. Consider them for comparative context:

1Synthesis of heterocycles by radical cyclisationJournal of the Chemical Society Perkin Transactions 1 · 2002
2A facile route to pyrroles, isoindoles and hetero fused analoguesJournal of the Chemical Society Perkin Transactions 1 · 2002
3Synthesis and optimization of tri(propylene glycol) glycerolate diacrylate cross-linked polystyrene resin in polypeptide synthesis: role of the macromolecular support in solid phase peptide synthesisJournal of the Chemical Society Perkin Transactions 1 · 2002
4Unusual hydrogen-bonding differences in stereoisomeric 6-C-alkylated cyclodextrinsElectronic supplementary information (ESI) available: IR spectra of compounds 5 and 7 in CH2Cl2 solution. See http://www.rsc.org/suppdata/p1/b2/b207033m/Journal of the Chemical Society Perkin Transactions 1 · 2002
5The Sharpless asymmetric aminohydroxylationJournal of the Chemical Society Perkin Transactions 1 · 2002
6A nucleophilic addition ring closure [NARC]-based synthesis of (+) -nonactic acidJournal of the Chemical Society Perkin Transactions 1 · 2002
7Titanium reagents for the alkylidenation of carboxylic acid and carbonic acid derivativesJournal of the Chemical Society Perkin Transactions 1 · 2002
8Stereocontrolled synthesis of glucosidic damascenone precursorsJournal of the Chemical Society Perkin Transactions 1 · 2002
9Nitro and related groupsJournal of the Chemical Society Perkin Transactions 1 · 2002
10Comparative study of base damage induced by gamma radiation and Fenton reaction in isolated DNAJournal of the Chemical Society Perkin Transactions 1 · 2002

More from Journal of the Chemical Society Perkin Transactions 1