A theoretical procedure for determining the specific volume of an inhomogeneous binary mixture having a large radius ratio is presented. The procedure is based on the hypothesis that the Furnas model holds on a local level. The methodology developed is demonstrated using two hypothetical compositional distribution functions. In one case the compositional distribution describes changes that occur from a completely unmixed to a completely mixed state. The second utilizes the normal distribution for describing smaller compositional variations.
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Messing et al. (1978) studied this question.
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