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The ν3 fundamental band of CH4 was studied by application of the Goody statistical band model to small frequency intervals within the band. The band parameters were established from low-resolution measurements, and the spectral absorption coefficient was derived for 42 frequencies in the band. The integrated band intensity was found to be 290±15 cm−2 atm−1 at 273°K.
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Finkman et al. (1967) studied this question.
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