A study of the detailed kinetics and particularly the CO2 quenching of CO fourth positive emission from active nitrogen has yielded individual rate coefficients for the energy transfer from N2(a1Πg), v = 0, 1 and 2 to CO(A1Π), v = 0 - 4. These do not follow any simple pattern. At high CO concentrations, an additional population of CO(A1Π), v = 1 and 6 from high levels of N2(a1Πg) and (a'1∑u-) occurs via the intermediacy of CO(I1∑-).
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Golde et al. (1972) studied this question.
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