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Designer saccharides: The cancer antigen Globo H hexasaccharide has been synthesized from designed building blocks in a rapid, stereoselective, and high-yielding manner by using the reactivity-based one-pot strategy (see scheme) guided by the OptiMer computer program. Bn=benzyl, Bz=benzoyl, ClBn=ortho-chlorobenzyl, NBz=para-nitrobenzoyl, NHTroc=2,2,2-trichloroethylcarbamate, PMP=para-methoxyphenyl.
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Burkhart et al. (2001) studied this question.
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