Outstanding catalytic activity for the selective oxidation of acrolein (see picture) is observed with a crystalline metal oxide, Mo3VOx (x≤11.1). The catalyst is synthesized from a solution containing pentagonal units of {Mo(Mo5O27)} (blue), which further react with molybdenum and vanadium species (red) to form a 3D metal oxide.
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Sadakane et al. (2007) studied this question.
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