The influence of various soaps and monomers on the rate of thermal decomposition of potassium peroxydisulphate has been investigated. It was found that all investigated compounds, except a fully fluorinated soap caused marked increases in the rate or peroxydisulphate disappearance. This finding should be considered in studies on the kinetics of polymerization in which peroxydisulphate is the initiator.
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Morris et al. (1968) studied this question.
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