Complex libraries composed of more than five thousand cyclopeptides can act as chiral selectors when added to the mobile phase in capillary electrophoresis. Cyclo‐hexapeptide sublibraries (such as those listed below) were used to achieve baseline separations of enantiomers of Nα‐dinitrophenyl (DNP) and 9‐fluorenylmethoxycarbonyl (FMOC) amino acids and Tröger's base. This approach can be used to identify selectors for difficult‐to‐separate racemates. equation image
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Jung et al. (1996) studied this question.
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