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The combination of [bis(acetoxy)iodo]benzene and thiocyanate anion in a polar, protic non nucleophilic solvent such as 1,1,1,3,3,3-hexafluoropropan-2-ol is able to perform an oxidative nucleophilic addition to alkenes, leading to acetoxy thiocyanate derivatives, stereoselectively and with good regioselectivity.
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MICO et al. (1997) studied this question.
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