Measurements of isothermal crystallization kinetics of poly(ethylene terephthalate) including defined solid nucleating agents have been performed by DSC method in broad temperature range. Based on the results and knowledge of growth rate of spherulities in PETP the nucleation rates were calculated. The mechanism of heterogeneous nucleation in PETP was analyzed. The results of the investigation were the basis for proposal of a modified model of heterogeneous nucleation in PETP.
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WLADYSLAW PRZYGOCKI (1982) studied this question.
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