Magnesium Hydroxide Dehydroxylation/Carbonation Reaction Processes: Implications for Carbon Dioxide Mineral Sequestration

Gas‐phase magnesium hydroxide carbonation processes were investigated at high CO 2 pressures to better understand the reaction mechanisms involved. Carbon and hydrogen elemental analysis, secondary ion mass spectrometry, ion beam analysis, X‐ray diffraction, and thermogravimetric analysis were used to follow dehydroxylation/rehydroxylation/carbonation reaction processes. Dehydroxylation is found to generally precede carbonation as a distinct but interrelated process. Above the minimum CO 2 pressure for brucite carbonation, both carbonation and dehydroxylation reactivity decrease with increasing CO 2 pressure. Low‐temperature dehydroxylation before carbonation can form porous intermediate materials with enhanced carbonation reactivity at reduced (e.g., ambient) temperature and pressure. Control of dehydroxylation/rehydroxylation reactions before and/or during carbonation can substantially enhance carbonation reactivity.