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April 1, 1997Chemistry Letters

Insertion of CO into a CH3-Pd Bond in a Heterodinuclear Complex (dpe)MePd-Co(CO)4. Preferential Insertion of Coordinated CO on a Cobalt Moiety

Atsushi Fukuoka Sumiko Fukagawa Masafumi Hirano Sanshiro Komiya

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Abstract

A palladium-containing heterodinuclear complex (dpe)MePd-Co(CO)4 shows higher reactivity toward CO insertion than PdMeCl(dpe) and (dpe)MePt-Co(CO)4 to give an acetyl complex (dpe)AcPd-Co(CO)4. The insertion of CO ligand in Co(CO)4 is a kinetically favorable process.

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Fukuoka et al. (1997) studied this question.

synapsesocial.com/papers/6a9e7130d9ca666ee02cb4e6 https://doi.org/10.1246/cl.1997.377

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