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A second-order nonlinear differential equation is developed to model the diffusion and heterogeneous recombination of atomic species in a porous medium. The model incorporates adsorption, thermal desorption and Eley–Rideal recombination of atoms on pore surfaces. Analytic solutions and numerical examples are presented, and their application to laboratory investigations of heterogeneous chemistry is discussed.
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Marschall et al. (2006) studied this question.
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