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The spectral distribution of both, excitation and emission of luminescence of ZnS:Mn with manganese on different lattice sites is investigated by dye laser spectroscopy. An unambiguous correlation of zero‐phonon lines due to Mn2+ in cubic and different axial lattice sites is given. The relative oscillator strength of the fluorescent transition of Mn2+ in different crystal sites is determined by exciting within the zero‐phonon transitions of the absorption and by registering the zero‐phonon lines in emission, which belong to the same lattice sites, respectively.
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Busse et al. (1979) studied this question.
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