New kid on the block: Unprecedented polystyrene-block-poly(methylenephosphine) copolymers are accessible from the reaction of living polystyrene with the phosphaalkene (see scheme; Mes=2,4,6-Me3C6H2). The living anionic polymerization of PC bonds represents a new development in phosphorus chemistry and opens up the possibility to synthesize functional phosphorus polymers of controlled architectures. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z602955_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Noonan et al. (2006) studied this question.
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