The first synthesis of the glucosinalbin and glucoaubrietin anions has been achieved by sulfonation and deacetylation of the thiohydroximates obtained by addition of tetraacetyl-glucopyranosyl mercaptan to p-acetoxyphenylacetonitrile oxide and p-methoxyphenyl-acetonitrile oxide.
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M. H. Benn (1965) studied this question.
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