A combination of high‐resolution spectroscopy and time‐of‐flight mass spectrometry was used for the first time to study the fundamental properties of supersonically expanded van der Waals complexes between (R)‐(+)‐1‐phneyl‐1‐propanol (PR) and the enantiomers of 2‐butanol (BR or BS) at the microscopic level. Chiral discrimination is based on the different fragmentation patterns of PRBR and PRBS or on the different bathochromic shift of their electronic band origin relative to that of pure PR.
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Pierini et al. (1997) studied this question.
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