The syntheses and X‐Ray analyses of three pentavalent organobismuth compounds are described; one of these compounds has a novel diphenylbis(trifluoroacetato)‐bismuthate anion with trigonal bipyramidal geometry and a stereochemically active lone pair. Analysis of these structures together with other data from the literature allows a mapping of the reaction coordinate for bismuth polyhedra.
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Barton et al. (1984) studied this question.
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