The chemical and electrochemical synthesis, X-ray crystal structure, magnetic characterization, absorption and luminescence spectra of (NBun4)3[Re6S8Cl6], the 23-electron cluster core member of the reversible redox couple [Re6S8Cl6]4––[Re6S8Cl6]3–· is reported.
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Guilbaud et al. (1999) studied this question.
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