All articles of this category The stereospecific total synthesis of (±)-virantmycin ( 1 ) and its diastereomer (±)- 2 were efficiently achieved, featuring an intramolecular nitrene-addition reaction as the key step, without ambiguity in the relative stereochemistry at the two chiral centers (C-2 and C-3).
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Morimoto et al. (1991) studied this question.